Reactions of trimethylsilyl isothiocyanate with aldehydes and acetals. Synthesis of symmetrically and unsymmetrically isothiocyanato-substituted ethers.

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概要

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• The reactions of trimethylsilyl isothiocyanate (TMSTC) with aldehydes catalyzed by Lewis acid gave α,α′-diisothiocyanato ethers in good to excellent yields. Similarly, unsymmetrical α-isothiocyanato ethers were obtained from the reactions of TMSTC with acetals in appropriate yields.

• 公益社団法人 日本化学会の論文

著者

• Nishiyama Kozaburo

  Department Of Applied Chemistry & Biochemistry Kumamoto University

• Oba Makoto

  Department of Chemistry, Tokyo Metropolitan University

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