Inverse Secondary Deuterium Kinetic Isotope Effect in Diels-Alder Reaction of Orthonaphtho [3.3] orthoanthracenophane with Maleic Anhydride

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概要

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• The Diels-Alderreactions of rigid [3.3] orthoanthracenophanes 1 and 2 with maleic anhydride and deuterium-labeled maleic anhydride-d_2, were studied. In the reaction of naphtophane 1, a large inverse secondary kinetic isotope effect (SDKIE) (kH_2/kD_2=0.78) was observed, while benzophane 2 shows a SDKIE similar to that of anthracene itself (kH_2/kD_2=0.95 and 0.96).

• 九州大学の論文
• 1996-11-12

著者

• Tashiro M

  Institute Of Advanced Material Study And Department Of Molecular Science And Technology Graduate Sch

• Mataka S

  Kyushu Univ. Kasuga

• Mataka Shuntaro

  Department Of Molecular Science And Technology Graduate School Of Engineering Sciences Kyushu Univer

• Mataka Shuntaro

  Institute Of Advanced Material Kyushu University

• Mataka Shuntaro

  Institute Of Advanced Material Study Kyushu University

• THIEMANN Thies

  Institute of Advanced Material Study, Kyushu University

• Thiemann T

  Institute Of Advanced Material Study Kyushu University

• TSUZUKI Hirohisa

  Center of Advanced Instrumental Analysis, Kyushu University

• Ma Jiang

  Department of Molecular Science and Technology, Graduate School of Engineering Sciences, Kyushu Univ

• Nishiyama Kozaburo

  Department of Material Science and Technology, Tokai University

• Thiemann Thies

  Faculty of Pharmacy, University of Coimbra

• Tsuzuki Hirohisa

  Center Of Advanced Instrumental Analysis Kyushu University

• Nishiyama Kozaburo

  Department Of Applied Chemistry & Biochemistry Kumamoto University

• Ma Jiang

  Department Of Molecular Science And Technology Graduate School Of Engineering Sciences Kyushu Univer

• Nishiyama Kozaburo

  Department Of Material Science And Technology Tokai University

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