Substitution reaction of organic halide by trimethylsilyl isothiocyanate: Formation of thiocyanate and its rearrangement to isothiocyanate.

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概要

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• The reaction of organic halide with trimethylsilyl isothiocyanate (TMSTC) gave thiocyanate <B>1</B> and its isomerized isothiocyanate <B>2</B>. Details of the substituion and the isomerization reactions were examined.

• 公益社団法人 日本化学会の論文

著者

• Nishiyama Kozaburo

  Department Of Applied Chemistry & Biochemistry Kumamoto University

• Oba Makoto

  Department of Chemistry, Tokyo Metropolitan University

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