Fries rearrangement of 1-methoxy-4-(4-methyl-2- and -3-pentenoyloxy)benzenes.

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概要

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• Not only rearrangement but also cyclization occurred in a Fries rearrangement of 1-methoxy-4-(4-methyl-2- and -3-pentenoyloxy)benzenes and gave 5,8-dihydroxy-4,4-dimethyl-3,4-dihydro-1(2<I>H</I>)-naphthalenone. The reduction and oxidation of the dihydronaphthalenone gave 5-hydroxy-8,8-dimethyl-5,6,7,8-tetrahydro-1,4-naphthalenedione and 8,8-dimethyl-7,8-dihydro-1,4,5(6<I>H</I>)-naphthalenetrione, respectively.

• 公益社団法人 日本化学会の論文

著者

• Tanoue Yasuhiro

  Department of Chemistry, Kyushu Institute of Technology

• Terada Akira

  Department of Chemistry, Faculty of Science, Osaka City University

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• Fries rearrangement of 1-methoxy-4-(4-methyl-2- and -3-pentenoyloxy)benzenes.

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