Synthesis of shikalkin (.+-.shikonin) and related compounds.
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概要
- 論文の詳細を見る
The key intermediate, 2-formyl-1,4,5,8-tetramethoxynaphthalene, was prepared through 1,4,5,8-tetramethoxynaphthalene, which was obtained from 1,5-naphthalenediol via three steps or from naphthazarin via one step. A total synthesis of shikalkin and dihydroshikalkin have been accomplished with this aldehyde via a side-chain introductions with Grignard reactions and the following demethylations.
- 公益社団法人 日本化学会の論文
著者
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Terada Akira
Department Of Computer Science Tokyo Institute Of Technology
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Sakamoto Hiroshi
Deparment Of Biology Faculty Of Science Kobe University
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Tanoue Yasuhiro
Department of Chemistry, Kyushu Institute of Technology
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Hatada Akira
Department of Chemistry, Kyushu Institute of Technology
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Terada Akira
Department of Chemistry, Kyushu Institute of Technology
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Sakamoto Hiroshi
Department of Chemistry, Kyushu Institute of Technology
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Terada Akira
Department of Chemistry, Faculty of Science, Osaka City University
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