Micellar catalytic effect on the base dissociation of methylamine studied by the ultrasonic absorption method.

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概要

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• Micellar catalytic effects on the base dissociation of methylamine have been studied by ultrasonic absorption method. The dissociation constant, the rate constants, and the volume change of the reaction were obtained in the absence and in the presence of SDS. The micellar catalytic effects observed for methylamine was smaller than those for amines of long alkyl chain, which was ascribed to the facts that the former is incorporated into the micellar ionic atmosphere in the concentrated micellar solution while the latters are solubilized into micelles.

• 公益社団法人 日本化学会の論文

著者

• Harada Shoji

  Faculty Of Engineering Osaka University

• Sano Takayuki

  Faculty of Science, Hiroshima University

• Yamashita Teruyo

  Daiichi College of Pharmaceutical Science

• Yano Hiroshige

  Daiichi College of Pharmaceutical Science

• Inoue Tadaomi

  Faculty of Engineering, Kinki University

• Yasunaga Tatsuya

  Faculty of Engineering, Kinki University

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