Asymmetric carbonyl addition and asymmetric polymerization assisted by axially chiral diamines give disparate ligand/product configurational correlations.
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概要
- 論文の詳細を見る
Organolithium reagents complexed with axially chiral biphenyl-substituted <I>N</I>,<I>N</I>,<I>N</I>′,<I>N</I>′-tetramethylethylenediamines (<B>1</B> and <B>2</B>) add to aldehydes in good enantioface selectivity. The pattern of the stereoselection, however, disagrees with that of the helical choice observed for the asymmetric polymerization of triphenylmethyl methacrylate with the same complexes.
- 公益社団法人 日本化学会の論文
著者
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SUDA Hiroshi
Department of Astronomy, The University of Tokyo
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Motoi Masatoshi
Department Of Chemistry And Chemical Engineering Faculty Of Engineering Kanazawa University
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Kanoh Shigeyoshi
Department Of Chemistry And Chemical Engineering Faculty Of Engineering Kanazawa University
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Kanoh Shigeyoshi
Department of Chemistry and Chemical Engineering, Faculty of Technology, Kanazawa University
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Muramoto Hiroki
Department of Chemistry and Chemical Engineering, Faculty of Technology, Kanazawa University
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Maeda Kazunobu
Department of Chemistry and Chemical Engineering, Faculty of Technology, Kanazawa University
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Kawaguchi Naotaka
Department of Chemistry and Chemical Engineering, Faculty of Technology, Kanazawa University
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Suda Hiroshi
Department of Applied Science, Faculty of Engineering, Tohoku University
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