Triethylamine-mediated generation of a synthetic equivalent of parent azomethine imine by condensation of ethyl 3-benzylcarbazate with paraformaldehyde.
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概要
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A synthetic equivalent of parent azomethine imine is accessible by simple heating of ethyl 3-benzylcarbazate with paraformaldehyde under reflux in toluene in the presence of triethylamine, which effectively suppresses the undesired formation of imine dimers. The resulting imines can be trapped with a variety of dipolarophiles.
- 公益社団法人 日本化学会の論文
著者
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Kanemasa Shuji
Institute Of Advanced Material Study Kyushu University
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Wada Eiji
Institute Of Advanced Material Study Kyushu University
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Tsuge Otohiko
Institute of Advanced Material Study, and Department of Molecular Science and Technology, Interdisciplinary Graduate School of Engineering Sciences
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Wada Eiji
Institute of Advanced Material Study, and Department of Molecular Science and Technology, Interdisciplinary Graduate School of Engineering Sciences, Kyushu University
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Tomoshige Naoki
Institute of Advanced Material Study, and Department of Molecular Science and Technology, Interdisciplinary Graduate School of Engineering Sciences, Kyushu University
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