The electrolytic reduction of p-substituted .ALPHA.-(methylsulfinyl)-.ALPHA.-(methylthio)acetophenones in acetonitrile.
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概要
- 論文の詳細を見る
<I>p</I>-Substituted α-(methylsulfinyl)-α-(methylthio)acetophenones (<B>1</B>) exhibit, on polarographic reduction, three waves. The two last waves correspond to the reductions of <I>p</I>-substituted α-(methylthio)acetophenones (<B>2</B>) and <I>p</I>-substituted acetophenones respectively. The macroelectrolysis at the first wave potential results in the formation of <B>2</B> in good yields in the presence of benzoic acid. The electrolytic reduction of <B>1</B> is characterized by the elimination of the methylsulfinyl group rather than by the deoxygenative reduction of the sulfoxide to the sulfide or the reduction of the carbonyl group.
- 公益社団法人 日本化学会の論文
著者
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KUNUGI AKIRA
Department of Analytical Chemistry, Tokyo College of Pharmacy
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Abe Kyo
Department of Chemistry, Faculty of Science, Osaka City University
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Takahashi Norimasa
Department of Applied Chemistry, Faculty of Engineering, Osaka City University
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Hirai Taketsugu
Department of Applied Chemistry, Faculty of Engineering, Osaka City University
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