Some properties of cyclopropenone oximes under Beckmann reaction conditions.
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概要
- 論文の詳細を見る
The reaction of diphenylcyclopropenone oxime (<B>1a</B>) with acetyl or tosyl isocyanate, carboxylic anhydrides, or nitrohalobenzenes yielded the cyclopropenone <I>O</I>-substituted oxime derivatives. Treating with thionyl bromide and chloride <B>1a</B> gave 3-haloacrylonitriles. Whereas <B>1a</B> as well as other cyclopropenone oximes, were stable under acidic conditions, heating in methanolic sodium hydroxide gave the ring-opened α,α-dimethoxyketones oximes.
- 公益社団法人 日本化学会の論文
著者
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Ogata Tsuyoshi
Department Of Operative Dentistry Tokyo Dental College
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Yoshida Hiroshi
Departmen Of Radiology School Of Medicine Asahikawa Medical University
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Yoshida Keisuke
Department of Applied Chemistry, Faculty of Engineering, Shizuoka University
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Totani Hiroyuki
Department of Applied Chemistry, Faculty of Engineering, Shizuoka University
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Matsumoto Kiyoshi
College of Liberal Arts and Sciences, Kyoto University
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Ogata Tsuyoshi
Department of Applied Chemistry, Faculty of Engineering, Shizuoka University
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