The reaction of wittig reagents with selenium. Formation of selenoaldehydes.
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概要
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The reaction of Wittig reagents with elemental selenium gave the corresponding selenoaldehydes which further reacted with other Wittig reagents to give the corresponding dimeric olefins in good yields. The selenoaldehydes formed afforded corresponding adducts by the reaction with dienes. These selenoaldehydes obtained by retro Diels–Alder reaction were also found to react with Wittig reagents to give the corresponding olefins in good yields.
- 公益社団法人 日本化学会の論文
著者
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Okuma Kentaro
Department Of Chemistry Faculty Of Science Fukuoka University
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Ohta Hiroshi
Department Od Cardiovascular Medicine Juntendo University
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IWATA Eiji
Department of Ophthalmology, Nagoya University Graduate School of Medicine
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KANEKO Isao
Department of Electronics Engineering, Gunma University
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Tachibana Yuji
Department of Chemistry, Faculty of Science, Fukuoka University
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Komiya Yasuo
Department of Chemistry, Faculty of Science, Fukuoka University
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