Ozone Fading of 2,2'-Dihydro Azo Copper Complex Dyes.
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概要
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The reactivities of dyes with ozone were in the following order, Acid Blue 74>disodium 1-(2-hydroxyphenylazo)-2-naphthol-3,6-disulfonate>Direct Yellow 12>Acid Orange 7>disodium 1-phenylazonaphthalene-3,6-disulfonate-2,2′-diolatocopper(II)>Mordant Red 3>Basic Green 4. The reaction of disodium 1-phenyl-azonaphthalene-3,6-disulfonate-2,2′-diolatocopper(II) with ozone was retarded by the introduction of electron-withdrawing groups and 8-sulfonato group. The potassium sulfonate dye was less reactive than the sodium one. Ozonization of l-phenylazonaphthalene-2,2′-diolatocopper(II) gave phenol, 2-naphthol, and phthalic anhydride.
- 公益社団法人 日本化学会の論文
著者
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Shibata Katsuyoshi
Departmentof Chemistry, Faculty of Engineering, Gifu University
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MURAMATSU Hiroshige
Department of Chemistry, Faculty of Engineering, Gifu University
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Matsui Masaki
Department Of Chemistry Faculty Of Engineering Gifu University
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Tsubota Kenjiro
Department of Chemistry, Faculty of Engineering, Gifu University
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