A Hydrogen Insertion Compound of Molybdenum Oxide Hydrate, H0.12-0.22MoO3H2O, and Its Formation Process from Hydrogen Molybdenum Bronze, HxMoO3.
スポンサーリンク
概要
- 論文の詳細を見る
Based on XRD and chemical analysis results, the hydrogen insertion compound of molybdenum oxide hydrate (H-hydrate) was suggested to be a genotypic compound of yellow molybdenum trioxide monohydrate, MoO<SUB>3</SUB>·H<SUB>2</SUB>O. H-hydrate was obtained in a hot HCl solution and in hot water from hydrogen molybdenum bronze, H<I><SUB>x</SUB></I>MoO<SUB>3</SUB>. The hydrogen bronze with <I>x≤</I>0.24 and the molybdenum species formed in the solution played a role in the formation of H-hydrate. In this process, a temporary dissolution of Mo<SUP>5+</SUP> was observed at the beginning of the formation.
- 公益社団法人 日本化学会の論文
著者
-
Sotani Noriyuki
College of Liberal Arts, Kobe University
-
Eda Kazuo
College of Liberal Arts, Kobe University
関連論文
- Decomposition of blue orthorhombic hydrogen molybdenum bronze, H0.30MoO3, by heating in vacuo and in helium gas.
- Structural and compositional changes of blue orthorhombic hydrogen molybdenum bronze, H0.30MoO3, by vacuum heating and catalytic activity for 1-butene isomerization.
- Structural and Compositional Changes of Hydrated Sodium Molybdenum Bronze by Heat Treatments in Air.
- Formation of Na0.9Mo6O17 in a solid-phase process. Transformations of a hydrated sodium molybdenum bronze, Na0.23(H2O)0.78MoO3, with heat treatments in a nitrogen atmosphere.
- A Hydrogen Insertion Compound of Molybdenum Oxide Hydrate, H0.12-0.22MoO3H2O, and Its Formation Process from Hydrogen Molybdenum Bronze, HxMoO3.
- Formation of a hydrogen insertion compound of hydrated molybdenum oxide from hydrogen molybdenum bronze.
- Infrared study of structural and compositional changes in orthorhombic hydrogen molybdenum bronze, H0.3MoO3, by heating in vacuo.
- Studies on the Hexagonal Hydrate of Molybdenum Trioxide. The Physical Properties of the Hydrate and Its Changes on Heat Treatments in Air, in Hydrogen, and in a Hydrogen–thiophene Mixture
- Carbon deposition on nickel from a mixture of ethylene and hydrogen.