Structural and compositional changes of blue orthorhombic hydrogen molybdenum bronze, H0.30MoO3, by vacuum heating and catalytic activity for 1-butene isomerization.
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概要
- 論文の詳細を見る
Orthorhombic bronze, H<SUB>0.30</SUB>MoO<SUB>3</SUB>, was decomposed by vacuum heating to MoO<SUB>2.86</SUB> With a rhombic MoO<SUB>3</SUB> structure. The surface area increased slightly with the increase in the rhombic structure in which vacancies were produced. An approximate linear relationship was found between the catalytic activity of 1-butene isomerization and the hydrogen content(<I>x</I>) in the samples which were treated in air at 65 °C or <I>in vacuo</I> below 220 °C. On the other hand, the activity above 220 °C increased with the formation of vacancies.
- 公益社団法人 日本化学会の論文
著者
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Yoshioka Yukio
Department Of Cardiology And Cardiac Surgery Higashi Nagano National Hospital
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Sotani Noriyuki
College of Liberal Arts, Kobe University
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Yoshida Noritetsu
Department of Chemistry, Faculty of Science, Kobe University
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Kishimoto Shozo
Department of Chemistry, Faculty of Science, Kobe University
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Yoshioka Yukio
Department of Chemistry, Faculty of Science, Kobe University
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