Theoretical study on the formation of spherical micelles.
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From the Tanford theory for the formation of spherical micelles and a modification of this theory, the aggregation number <I>n</I><SUB>w</SUB> and monomer concentration <I>x</I><SUB>1</SUB> are calculated as a function of total surfactant concentration <I>x</I>. The definition of cmc of <I>d</I><SUP>3</SUP><I>x</I><SUB>1</SUB>⁄<I>dx</I><SUP>3</SUP>=0 is adequate. Empirical equations for the estimation of <I>n</I><SUB>w</SUB> and cmc are obtained.
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