The Density and Molar Volume of a Binary Liquid, B<SUB>2</SUB>O<SUB>3</SUB>-H<SUB>2</SUB>O
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The density of the binary B<SUB>2</SUB>O<SUB>3</SUB>-H<SUB>2</SUB>O liquid system with concentrations of from 4.9 to 83.0 mol% B<SUB>2</SUB>O<SUB>3</SUB> has been measured, and the mean volume expansivity has been calculated. The molar volume and the expansivity of this system has then been compared with those of other binary borates. The experimental results suggest a change in the boron-to-oxygen coordination number between the 3B<SUB>2</SUB>O<SUB>3</SUB>·H<SUB>2</SUB>O and B<SUB>2</SUB>O<SUB>3</SUB>·H<SUB>2</SUB>O compositions. The thermal expansivity of this system shows a different trend from those of alkali borate melts.
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