Polarography of Halides in Dimethylformamide. IV. The Stability Constants of the Halo Complexes of Mercury (II)
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概要
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The overall stability constants (β) of mercuric halide and the tri- and tetrahalogenomercurate ions in dimethylformamide containing 0.1 M tetraethylammonium perchlorate were evaluated by the polarographic method at 25°C. The values of log β obtained were: 24.16 for HgCl<SUB>2</SUB>, 31.23 for HgCl<SUB>3</SUB><SUP>−</SUP>, 34.57 for HgCl<SUB>4</SUB><SUP>2−</SUP>, 24.17 for HgBr<SUB>2</SUB>, 31.62 for HgBr<SUB>3</SUB><SUP>−</SUP>, 34.73 for HgBr<SUB>4</SUB><SUP>2−</SUP>, 25.93 for HgI<SUB>2</SUB>, 33.34 for HgI<SUB>3</SUB><SUP>−</SUP>, and 36.02 for HgI<SUB>4</SUB><SUP>2−</SUP>.
- 公益社団法人 日本化学会の論文
著者
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Date Yoshio
Department of Agricultural Chemistry, Faculty of Agriculture, Shimane University
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Matsui Yoshihisa
Department of Agricultural Chemistry, Faculty of Agriculture, Shimane University
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