Thermal and Photolytic Decompositions of Azobis(2-phenoxy)-2-propane
スポンサーリンク
概要
- 論文の詳細を見る
Thermal and photolytic decompositions of azobis(2-phenoxy)-2-propane have been studied. More than half of the 2-phenoxyprop-2-yl radicals thus produced thermally cause the phenyl group to migrate from oxygen to the carbon, followed by elimination of the methyl group. Most of the remaining radicals abstract hydrogen from the solvent. When phenyl ether is employed as a solvent, homolytic aromatic substitution takes place yielding isopropylbenzene derivatives. It is shown by mechanistic consideration, although not completely decisively, that this is a new type of reaction in the sense that a part of the leaving group constitutes a part of the entering group.
- 公益社団法人 日本化学会の論文
著者
-
Ohnishi Yutaka
Sagami Chemical Research Center
-
Kito Noboru
Sagami Chemical Research Center
-
Ohno Atsuyoshi
Sagami Chemical Research Center
関連論文
- Thiocarbonyl Compounds as Potential Scavengers of Carbon Radicals
- Reduction by a model of NAD(P)H. XIV. Mechanistic consideration on the role of metal ion.
- Thermal and Photolytic Decompositions of Azobis(2-phenoxy)-2-propane
- Thermal and Photolytic Decompositions of Azobis(2-phenylthio)-2-propane
- Photocycloaddition of Thiocarbonyl Compounds to Multiple Bonds. VII. The Reaction of Thiobenzophenone with Acetylenic Compounds
- Studies on Electron Spin Resonance Spectra of 2-Substituted Prop-2-yl Radicals
- Photochemical Reduction of Thiobenzophenone. Reduction by Dihydroaromatic and Related Compounds
- One-electron reduction of 1-benzyl-3-carbamoylpyridinium as a NAD+ model.
- Reduction by a model of NAD(P)H. XV. Kinetics for the reduction of methyl benzoylformate.