Thermal and Photolytic Decompositions of Azobis(2-phenylthio)-2-propane
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概要
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Thermal and photolytic decompositions of azobis(2-phenylthio)-2-propane have been studied. The reaction mechanisms have been discussed on the basis of products. Almost all reactions of 2-phenylthioprop-2-yl radicals produced from the azo compound photolytically proceed with in-cage processes. The ratio, disproportionation/dimerization, predicts qualitatively that the radical center of the free radical is more electronegative than that of the corresponding oxygen analog.
- 公益社団法人 日本化学会の論文
著者
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Ohnishi Yutaka
Sagami Chemical Research Center
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Kito Noboru
Sagami Chemical Research Center
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Ohno Atsuyoshi
Sagami Chemical Research Center
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