Photochemical Reduction of Thiobenzophenone. Reduction by Dihydroaromatic and Related Compounds
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Photochemical reduction of thiobenzophenone by 1,4-dihydrobenzene, 1,4-dihydronaphthalene, 9,10-dihydroanthracene, 1,3,5-cycloheptatriene, and acridane was studied. Relative reactivities and product analyses have revealed that the reaction is initiated by hydrogen-abstraction (one-electron-transfer followed by a proton migration) with thiobenzophenone in the n,π<SUP>*</SUP> triplet state. Inability of diphenylmethane to undergo the reaction can be interpreted by means of this mechanism.
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