The Synthesis and Photo Reaction of 7,11-Dimethyl-1,6,10-dodecatrien-3-one
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概要
- 論文の詳細を見る
For the purpose of constructing a pinene skeleton (I), a promising intermediate for the synthesis of bergamotenes (III), the vinyl ketone (II), was synthesized from geranyl bromide (IV) by the application of Meyer's method, followed by a Grignard reaction with vinylmagnesium bromide and subsequent oxidation. The irradiation of II in absolute ether afforded an unexpected keto ether (X) in a low yield; it was characterized by means of a deuterium-exchange reaction and physical methods. No other product except X was isolated from the photoreaction mixture of II.
- 公益社団法人 日本化学会の論文
著者
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Kitahara Yoshio
Department Of Chemistry Faculty Of Science Tohoku University
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Maeda Hideo
Department Of Neuropsychiatry School Of Medicine Sapporo Medical University
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Kato Tadahiro
Department of Applied Microbial Technology, Kumamoto Institute of Technology
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Tsunakawa Mitsuaki
Department of Chemistry, Faculty of Science, Tohoku University
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Maeda Hideo
Department of Chemistry, Faculty of Science, Tohoku University
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