The Thermal Reaction of Hydrogen and Nitric Oxide

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概要

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• The kinetics of the H<SUB>2</SUB>–NO pyrolysis was studied at 400°C; the reaction was found to be first-order in H<SUB>2</SUB> and to be independent of NO. It is suggested that the reaction proceeds by means of a free-radical chain mechanism: H<SUB>2</SUB>+NO(surface)→HNO+H(1), H+NO\rightleftharpoonsHNO (2), 2HNO→2OH+N<SUB>2</SUB> (3) OH+H<SUB>2</SUB>→H<SUB>2</SUB>O+H(4) and 2HNO→H<SUB>2</SUB>O+N<SUB>2</SUB>O(5). This reaction scheme resembles that proposed for the CH<SUB>2</SUB>O–NO pyrolysis at 500°C except for the initiating step (1), which takes place on the wall of the vessel in the H<SUB>2</SUB>–NO pyrolysis.

• 公益社団法人 日本化学会の論文

著者

• Tadasa Kohji

  Faculty of Liberal Arts and Sciences, University of Osaka Prefecture

• Imai Naomi

  Faculty of Liberal Arts and Sciences, University of Osaka Prefecture

• Inaba Tetsuo

  Faculty of Liberal Arts and Sciences, University of Osaka Prefecture

関連論文

• Photolysis of formaldehyde in the presence of nitric oxide.
• The Thermal Decomposition of Formaldehyde in the Presence of Nitric Oxide
• Thermal decomposition of dimethyl ether in the presence of nitrogen oxide.
• The Thermal Reaction of Hydrogen and Nitric Oxide
• The mercury-photosensitized reaction of hydrogen with nitric oxide.

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