Vinyl Polymerization. 327. Determination of the Initiating Radical Species in Polymerization with a Dimethylmercury and Copper(II)-Ion System
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概要
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Dimethylmercury was found to give a methyl radical (·CH<SUB>3</SUB>) by the reaction with Cu(II)-ion in the presence of water. Generation of ·CH<SUB>3</SUB> was proved by scavenging with 1,3,5,-triphenylverdazyl. Radical polymerization of methyl methacrylate and acrylonitrile was carried out with the system dimethylmercury/water/Cu(II)or Fe(III)-ion.
- 公益社団法人 日本化学会の論文
著者
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Ouchi Tatsuro
Department Of Applied Chemistry Faculty Of Engineering Kansai University
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Nakamura Yoshiaki
Department Of Aeronautical Engineering Nagoya University
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OUCHI Tatsuro
Department of Applied Chemistry, Faculty of Engineering, Kansai University
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Imoto Minoru
Department of Applied Chemistry Faculty of Engineering Osaka City University
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