The Role of the Promoting Mode in Nonradiative Transitions in Large Molecules
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概要
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A rate expression for the intramolecular nonradiative transition where a promoting mode acts also as an accepting mode at the same time has been derived within the statistical limit. The dependence of the nonradiative transition rate on the shift of the equilibrium point of the promoting mode in the relevant electronic states, <I>Δ</I><SUB>p</SUB>, has been examined for two cases, i) excited \rightsquigarrow ground states and ii) excited \rightsquigarrow excited states, in aromatic hydrocarbons which satisfy the above condition.
- 公益社団法人 日本化学会の論文
著者
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Fujimura Yuichi
Department Of Chemistry Graduate School Of Science Tohoku University
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Nakajima Takeshi
Department of Chemistry Faculty of Science Tohoku University
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