Oxidation of a Conductive Polymer-TCNQ Salt with Atmospheric Oxygen

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概要

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• The oxidation reaction of conductive poly-4-vinylpyridinium (P4VP<SUP>+</SUP>) tetracyano-<I>p</I>-quinodimethanide(TCNQ<SUP>\newdot</SUP>) with oxygen has been studied. The main product of this reaction is found to be α,α-dicyano-<I>p</I>-toluoylcyanide. An interesting difference in reactivity was observed between the polymer salt and the ethanol solution of the monomer salt.

• 公益社団法人 日本化学会の論文

著者

• Nakatani Kenji

  Department Of Advanced Materials Science Graduate School Of Frontier Science The University Of Tokyo

• Tsubomura Hiroshi

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• Nakatani Kenji

  Department of Chemistry, Faculty of Engineering Science, Osaka University

• Sakata Tadayoshi

  Department of Chemistry, Faculty of Engineering Science Osaka University

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