Sum rule consideration of molecular photoelectron spectra: s-type bands of butenes.
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概要
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The s-type photoelectron bands of <I>cis</I>-, <I>trans</I>-2-butene, and 2-methylpropene in the gaseous phase have been measured in the region 17–27 eV by a He(II) resonance lamp which was constructed for the present purpose. The vertical ionization energies obtained here from the s-type bands have been interpreted with the H\ddotuckel method involving the Coulomb integrals of carbon 2s atomic orbitals which were estimated on the basis of the idea of sum rule from the available He(II) data of many other hydrocarbons reported by Potts <I>et al</I>.
- 公益社団法人 日本化学会の論文
著者
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Katsumata Shunji
Physical Chemistry Laboratory Institute Of Applied Electricity Hokkaido University
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Kimura Katsumi
Physical Chemistry Laboratory Institute Of Applied Electricity Hokkaido University
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