HeI and HeII photoelectron study of N2O4.
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概要
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A 304 Å HeII photoelectron spectrum of N<SUB>2</SUB>O<SUB>4</SUB> in the gaseous phase has been deduced in the region up to 29 eV from a HeI spectrum of NO<SUB>2</SUB>–N<SUB>2</SUB>O<SUB>4</SUB> mixture obtained with a nozzle beam technique, indicating three new maxima in the region between 20 and 29 eV. A 584 Å Hel spectrum of N<SUB>2</SUB>O<SUB>4</SUB> was also obtained here. From a comparison of the HeI and HeII spectra of N<SUB>2</SUB>O<SUB>4</SUB> below 20 eV, it was confirmed that two ionization bands exist at 16.5 and 18.2 eV which appear as shoulders in the HeII spectrum. At least fourteen ionization bands have been identified from the HeII spectrum in the region studied. The thirteen bands below 24 eV have been assigned on the basis of a recent Green's function study of von Niessen <I>et al</I>.
著者
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Kimura Katsumi
Physical Chemistry Laboratory Institute Of Applied Electricity Hokkaido University
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Achiba Yohji
Physical Chemistry Laboratory, Institute of Applied Electricity, Hokkaido University
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Achiba Yohji
Physical Chemistry Laboratory, Institute of Applied Electricity Hokkaido University
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Nomoto Katsunori
Physical Chemistry Laboratory, Institute of Applied Electricity, Hokkaido University
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