Magnetic cross-over in hexa-coordinate iron(II) complexes of several Schiff bases.
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概要
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Iron(II) complexes with the Schiff bases of 6-methyl-2-pyridinecarbaldehyde and 2-quinolinecarbaldehyde, and with α,α′-diimine were prepared. The M\ddotossbauer spectra and magnetic susceptibilities of the complexes, Fe(cbi)<SUB>2</SUB>(NCS)<SUB>2</SUB>·<SUP>2</SUP>/<SUB>3</SUB>CHCl<SUB>3</SUB>, Fe(tbi)<SUB>2</SUB>(NCS)<SUB>2</SUB>·CHCl<SUB>3</SUB>, Fe(mpmea)<SUB>2</SUB>(ClO<SUB>4</SUB>)<SUB>2</SUB>, and Fe(mepma)<SUB>3</SUB>(ClO<SUB>4</SUB>)<SUB>2</SUB>, were studied in the range of 80–298 K. It was found that these complexes show a <SUP>5</SUP>T<SUB>2</SUB>-<SUP>1</SUP>A<SUB>1</SUB> spin transition in the solid state.
- 公益社団法人 日本化学会の論文
著者
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Nishida Yuzo
Department Of Chemistry Faculty Of Science Yamagata University
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Maeda Yonezo
Department Of Chemistry And Physics Graduate School Of Sciences Kyushu University
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Takashima Yoshimasa
Department Of Chemistry Faculty Of Science Kyushu University
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Maeda Yonezo
Department of Chemistry, Faculty of Science 33, Kyushu University
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Shite Shunji
Department of Chemistry, Faculty of Science 33, Kyushu University
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