Syntheses and electronic spectra of 2,2'-isopropylidenedi-8-quinolinol, its nickel(II), and copper(II) chelates.
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概要
- 論文の詳細を見る
The title ligand, which contains two 8-quinolinol (oxine) functions in one molecule, and the Ni(II) and Cu(II) chelates have been synthesized and characterized. Visible and ultraviolet spectra of the chelates and the ligand in several solvents have been measured. Square-coordination of the ligand to the metal has been revealed by a comparison of the d-d bands between the chelates and quadridentate Schiff base chelates in the literature. Intraligand transition bands of the title chelates and the solvent effects on the frequency shifts have been compared with those of the ligand, 8-hydroxy-1-methylquinolinium hydroxide, bis(8-quinolinolato)palladium(II), -copper(II), and -nickel(II), and have been discussed.
- 公益社団法人 日本化学会の論文
著者
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Miura Akira
Department Of 2nd Cardiology Wakayama Medical Center
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Miura Masayoshi
Department Of Kidney Transplant Surgery Sapporo City General Hospital
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Yamamoto Yoshinori
Department Of Chemistry Faculty Of Science Tohoku University
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Takei Shinsuke
Department of Industrial Chemistry, Faculty of Engineering, Ibaraki University
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Takei Shinsuke
Department of Applied Chemistry, Faculty of Engineering, Tohoku University
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Kawamata Akira
Department of Industrial Chemistry, Faculty of Engineering, Ibaraki University
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Miura Masayoshi
Department of Industrial Chemistry, Faculty of Engineering, Ibaraki University
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