芳香族溶媒中デセン-酢酸第二水銀付加体の熱および光反応によるアリール誘導体の合成 (第1報) : フェニルおよびトリル誘導体の合成

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Thermal and photochemical syntheses of aryl derivatives with highly aliphatic chains were examined and the following results were obtained.<BR>1) The thermal reaction of decene-mercuric acetate adduct with benzene affords 1-phenyl-2-decene (yield 18.7%) as the main product, while the photochemical reaction affords 1-phenyl-1-decene (3.6%), 1-phenyl-2-decene (11.3%), 1-phenyl-3-decene (2.6%) and 1-phenyl-4-decene (1.6%).<BR>2) The thermal reaction of decene-mercuric acetate adduct with toluene affords 1- (2-methylphenyl) -2-decene (18.0%) and 1- (4-methyl-phenyl) -2-decene (23.5%) as main products, while the photochemical reaction gives 1- (3-methylphenyl) -decane (22.8%) and 1- (4-methylphenyl) -decane (31.3%).<BR>3) These products would be formed through heterolytic cleavage of aryl- (acetoxymercury) -decane with demercuration in the thermal process, while through homolytic cleavage in the photochemical process.
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