ベンズアルデヒド液相光酸化反応における過安息香酸の収率の解析

概要

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To study the superiority of applying photochemical reaction to a system which is operated preferably at lower temperatures, photooxidation of benzaldehyde in liquid phase was made by using a bubble column photo-reactor illuminated from outside. The yield of perbenzoic acid was analysed experimentally and theoretically. Overall reaction rates were obtained for photodecomposition of perbenzoic acid. The yield of perbenzoic acid was increased in the region where chemical reaction was the rate-determining step with the light intensity as low as possible.
社団法人化学工学会の論文