Correlation of multiphase equilibria for asymmetric mixtures by a unified model.
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概要
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The simple DDLC-EOS unified model proposed in the previous paper was extended to describe the multiphase equilibrium behavior of highly asymmetric mixtures.<BR>Liquid–liquid equilibrium data of 25 binary and 5 ternary systems as well as vapor–liquid–liquid equilibrium data of five binary systems were correlated with this model and the Soave–Redlich–Kwong equation.<BR>Results show that for systems consisting of associating substances, fitting accuracies of the proposed model have been significantly improved.<BR>For systems of alkanes or alkylbenzenes with carbon dioxide or ethane as a common component, the average deviations of this model were also found to be lower than those of the conventional method with either temperature-independent or temperature-dependent binary interaction parameters.
- The Society of Chemical Engineers, Japanの論文
著者
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Dong Xue
Department of Pharmacology, School of Pharmaceutical Sciences, Shandong University
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Zheng Xi-yin
Department Of Chemical Engineering Faculty Of Engineering Kyushu University
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WU GUANG-WEN
Department of Chemical Engineering, Dalian Institute of Technology, People''s Republic of China
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ZHANG NAI-WEN
Department of Chemical Engineering, Dalian Institute of Technology, People''s Republic of China
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Wang Wei
Department of Anesthesiology, China-Japan Friendship Hospital, the Chinese Ministry of Health, Beijing, China
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