Photoswitching of electron transfer property of diarylethene-viologen linked molecular layer constructed on a hydrogen-terminated Si(111) Surface
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概要
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An organic monolayer with diarylethene and viologen moieties as a photochromic and an electroactive group, respectively, was constructed on a hydrogen-terminated Si(111) surface by sequential surface reactions. Photoswitching behaviour of electron transfer from the Si electrode to viologen moiety, larger and smaller current after UV and visible irradiation, respectively, was observed. This photoswitching behaviour can be explained by change in molecular conductivity of diarylethene moiety, which separates Si surface and viologen moiety, induced by ring closing and opening UV and visible irradiation, respectively.
- Elsevier B.V.の論文
- 2009-11-30
著者
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UOSAKI Kohei
Division of Chemistry, Graduate School of Science, Hokkaido University
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Uosaki Kohei
Division Of Chemistry Graduate School Of Science Hokkaido University
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Uosaki Kohei
Department Of Chemistry Faculty Of Science Hokkaido University
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