P18 リチウムイオン二次電池用鉄系正極材料Fe_3PO_7の超音波照射合成(ポスターセッション)

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Iron is expected as a positive electrode material because of its large Clarke number. In this reason, we have been interesting in iron based materials and been studying. In this time we focused on Fe_3PO_7. The theoretical capacity as cathode is 777mAh/g. Its large capacity is very attractive to compare to present materials being used as lithium ion batteries (LiCoO_2: 274mAh/g, LiMn_2O_4: 148mAh/g). The literature shows that Fe_3PO_7 was prepared by the two-step solid-state reaction. At first stoichiometric amounts of Fe_2O_3 and (NH_4)_2HPO_4 powders are mixed and heated 950 degrees Celsius for 12hour to synthesize FePO_4. Fe_2O_3 and FePO_4 are mixed and preheated 950 degrees Celsius for 12hour and finally heated at 1050 degrees Celsius and finally Fe_3PO_7 is prepared. Fe_3PO_7 requires a lot of time and high sintered temperature. To improve these problems, we have been studying about an easily synthesis method of Fe_3PO_7. In this study, we used the sonochemical method and try to obtain Fe_3PO_7 by one step reaction.
日本ソノケミストリー学会の論文
2006-10-27