No.21 石炭燃焼場からの窒素酸化物放出に対する排ガス再循環の影響(ガス化・燃焼・液化(2))

概要

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Currently, it becomes increasingly necessary to decrease CO_2 emissions from fossil fuel combustion processes, because they are major contributors to the global warming. Oxy-fuel coal combustion has drawn attention as useful technique to achieve carbon dioxide capture and storage (CCS). This is the technique that enriches CO_2 in exhaust gas by the flue gas recirculation with additional pure O_2 to combustion atmosphere, which makes easy to capture and liquidize CO_2 downstream. However, there have been few reports about behaviors of various environmental pollutants in oxy-fuel coal combustion with the flue gas recirculation. In this study, we experimentally estimated effects of NO and N_2O recirculation with CO_2 by a drop tube furnace equipment. In addition, we simulated NO and N_2O formations under oxy-fuel coal combustion condition by elementary reaction analysis, and then we discussed mechanism for the formation of NOX.
2012-10-15