Transformation of Grayanotoxin III to the 1,5-seco-Grayanotoxin Derivative, Grayanol B(Organic Chemistry)
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概要
- 論文の詳細を見る
Treatment of grayanotoxin (G) III with pyruvic acid in methanol gave the Δ^<1(10)>-1,5-seco-G derivative. Photo-sensitized oxygenation of Δ^<1(10)>-1,5-seco-G under UV light irradiation in methanol gave the 1(S)-perhydroxy- and 1(S)-hydroxy-1,5-seco-G derivatives. The IR and NMR data for Δ^<1(10)>-1(S)-hydroxy-1,5-seco-G were identical with those of natural grayanol B described in the literature.
- 社団法人日本農芸化学会の論文
- 1991-11-23
著者
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TERAI Tadamasa
Department of Applied Chemistry, Osaka Institute of Technology
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GOTO Kunio
Department of Information and Telecommunication Engineering, Nanzan University
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Terai Tadamasa
Department Of Applied Chemistry Osaka Institute Of Technology
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KIYONO Koushi
Department of Applied Chemistry, Osaka Institute of Technology
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Kiyono Koushi
Department Of Applied Chemistry Osaka Institute Of Technology
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Goto Kunio
Department Of Applied Chemistry Faculty Of Engineering Osaka Institute Of Technology
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