アルカリ性ペルオキソニ硫酸カリウム分解/塩化バナジウム還元を用いるジアゾ化カップリング反応による河川水中の全窒素測定

概要

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A convenient method was proposed for the spectrophotometric determination of total nitrogen in sewage and river-water samples. Each water sample was taken into glass bottles with screw caps and then heated at 120℃ for 30 min after the addition of potassium peroxodisulfate, by which nitrogen-containing compounds were quantitatively oxidized into nitrate. The determination of the resulting nitrate was performed by measuring the absorbance at 540nm after a diazotization coupling reaction of N-naphthylethylenediamine and sulfanylamide in the presence of nitrite generated from the reduction of nitrate with vanadium chloride. The proposed method could be applied to the determination of total nitrogen in sewage and river-water samples. Analytical data obtained by the proposed method were highly correlated to those determined by the UV method (JIS method). The sensitivity of the proposed method is superior to those of spectrophotometric methods reported so far.
社団法人日本分析化学会の論文
2006-04-05