An X-ray Study on the Structure of Cobalt Dichloride Hexahydrate

スポンサーリンク

概要

• 論文の詳細を見る

• The crystal structure of CoCl_2・6H_2O has been determined by the X-ray single crystal method. The unit cell is monoclinic with a=10.34A, b=7.06A, c=6.67A and β=122゜20'. The space group is C^2_<2h>-C2/m and the unit cell contains two molecules. Two Cl^- ions and four water molecules are octahedrally coordinated to Co^<2+> ion to form the group [CoCl_2・4H_2O]. These groups are held together parallel to the b axis by O…H-O type hydrogen bonds. The other two water molecules of the formula unit are far from Co^<2+> ion. The crystal has the layer structure parallel to (001), and this causes the perfect cleavage. The structure proposed for this salt by Stroganov et al. seems to be incorrect.

• 東北大学の論文

著者

• Mizuno Joji

  The Research Institute For Iron Steel And Other Metals

関連論文

• The Crystal Structure of CoCl_2・6H_2O
• An X-ray Study on the Structure of Cobalt Dichloride Hexahydrate
• Dependence of the Intermetallic Diffusion Coefficient upon Concentration
• On the Sintering Velocity of Powdered Metals. I : A Mixture of Nickel Powder and Copper Powder
• On the Twin Structure of Nickel Films Electrodeposited on Single Crystals of Copper
• An X-ray Study on the Structure of Cobalt Dichloride Hexahydrate

スポンサーリンク