An X-ray Study on the Structure of Cobalt Dichloride Hexahydrate

スポンサーリンク

概要

• 論文の詳細を見る

• The crystal structure of CoCl_2・6H_2O has been determined by the X-ray single crystal method. The unit cell is monoclinic with a=10.34Å, b=7.06Å, c=6.6Å and β=122°20´. The space group is C^3_<2h>〜C2/m and the unit cell contains two molecules. Two Cl^- ions and four water molecules are octahedrally coordinated to C0^<2+> ion to form the group [CoCl_2・4H_2O].These groups are held together parallel to the b axis by O...H-O type hydrogen bonds. The other two water molecules of the formula unit are far from C0^<2-> ion. The crystal has the layer structure parallel to (001), and this causes the perfect cleavage. The structure proposed for this salt by Stroganov et al. seems to be incorrect.

• 社団法人日本物理学会の論文
• 1960-08-05

著者

• Mizuno Joji

  The Research Institute For Iron Steel And Other Metals

関連論文

• The Crystal Structure of CoCl_2・6H_2O
• An X-ray Study on the Structure of Cobalt Dichloride Hexahydrate
• Dependence of the Intermetallic Diffusion Coefficient upon Concentration
• On the Sintering Velocity of Powdered Metals. I : A Mixture of Nickel Powder and Copper Powder
• On the Twin Structure of Nickel Films Electrodeposited on Single Crystals of Copper
• An X-ray Study on the Structure of Cobalt Dichloride Hexahydrate

スポンサーリンク