Note on the Free Volume of a Liquid

スポンサーリンク

概要

• 論文の詳細を見る

• Assuming the Hildebrand's relations concerning the internal energy of liquid and using the Clausius' virial theorem, a general equation of state of liquid was obtained. Combining this equation and the partition function of liquid, the free volume was derived as the function of molal volume of liquid. This results were compared with the Eyring's free volume of liquid in the case of ethyl ether. The disagreement between the two kinds of the free volumes is due to the neglect of dependency of the dimension of molecule upon the molal volume of the liquid. In conclusion, the author wishes to express his hearty thanks to Prof. E Kanda for his helpful advices and kind guidance through this work and also to T. Sugawara and T. Haseda for their valuable discussions.

• 東北大学の論文

著者

• Nomura Yokan

  The Research Institute For Iron Steel And Other Metals

関連論文

• Studies on the Discharge Reaction in Liquid Air. I : On the Discharge Reaction Products
• Some Experiments on the Explosive Reaction between Liquid Oxygen and Acetylene : Preliminary Research on Explosion of Liquid Oxygen
• On the Explosion of Air-Rectifying Apparatus. II
• On the Explosion of Air-Rectifying Apparatus. III : On the Initial Step of the Explosive Reaction between Ozone and Ethylene at Low Temperatures and Low Pressures
• Studies on the Discharge Reaction in Liquid Ari. II : On the Thermal Secondary Reaction
• Note on the Free Volume of a Liquid
• Studies on the Discharge Reaction in Liquid Air. III : On the Mechanisms of Nitric Oxide- and Ozone-Formation

スポンサーリンク