Studies on the Discharge Reaction in Liquid Ari. II : On the Thermal Secondary Reaction

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概要

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• The thermal reactions under discharge and reactions between the discharge reaction products during the rise of temperature after discharge were discussed from the following thermal reactions : 1) between NO and (NO_2)_2 above -85℃, 2) between nitrogen trioxide and oxygen above -80℃, 3) between NO and oxygen at temperatures slightly above the boiling point of oxygen and very violent reaction at -165℃, 4) explosive reaction between nitrogen trioxide and ozone at -100℃, 5) explosive reaction between (NO_2)_2 and ozone at -40℃. The reactions 4) and 5) sometimes proceeded nonexplosively forming N_2O_5 and oxygen. The green product of the discharge reaction was compared with the product of the similar colour obtained by passing NO into liquid oxygen, and the difference between them was ascertained. The compound such as NO_3 or N_3O_4, which had been believed by other authors to be a product of the latter reaction was not detected.

• 東北大学の論文

著者

• Nomura Yokan

  The Research Institute For Iron Steel And Other Metals

関連論文

• Studies on the Discharge Reaction in Liquid Air. I : On the Discharge Reaction Products
• Some Experiments on the Explosive Reaction between Liquid Oxygen and Acetylene : Preliminary Research on Explosion of Liquid Oxygen
• On the Explosion of Air-Rectifying Apparatus. II
• On the Explosion of Air-Rectifying Apparatus. III : On the Initial Step of the Explosive Reaction between Ozone and Ethylene at Low Temperatures and Low Pressures
• Studies on the Discharge Reaction in Liquid Ari. II : On the Thermal Secondary Reaction
• Note on the Free Volume of a Liquid
• Studies on the Discharge Reaction in Liquid Air. III : On the Mechanisms of Nitric Oxide- and Ozone-Formation

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