Ultra-Fine Spherical Particles of γ-Alumina: Electron Microscopy of Crystal Structure and Surface Morphology at Atomic Resolution
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概要
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The γ-alumina particles are produced by a dry method developed by the author. Three types of structures, tentatively called δ' (orthorhombic; Pmn2_1; a=8.2, b=16.4, c=11.8Å), θ_1 (monoclinic; B2/b; a=11.1, b=12.1, c=17.7Å, β=103°) and θ_2 (monoclinic, B2/m; a=11.1, b=12.1, c=2.9 Å, β=103°) are found. The particle is spherical but facetted with flat {111} and {100} surfaces; {110} surfaces consist of many small {111} facets. As a new approach to ceramics and catalysis research, surface morphology of a neck portion of two coalescing particles, and clusters of Rh_6(CO)_<16> impregnated on the particles are demonstrated for the first time.
- 社団法人応用物理学会の論文
- 1984-06-20
著者
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Iijima Sumio
Research And Development Group Nec Corporation
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IIJIMA Sumio
Research Development Corporation of Japan, c
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- Ultra-Fine Spherical Particles of γ-Alumina: Electron Microscopy of Crystal Structure and Surface Morphology at Atomic Resolution