ESR Study of Silver Chloride Crystals Doped with Sulphur Ions and Mercury Ions
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概要
- 論文の詳細を見る
Sulphur centers in silver chloride crystals are studied by ESR measurements and also observation of their kinetic behaviors. The paramagnetic centers produced by illumination have a symmetry axis of <100> and g values of g_&⫽=1.999 and g_&⊥=2.03l. They are ascribed to AgS radicals substituting for AgCl molecules in the crystal. The activation energy of formation of the photoproduced ESR signals is 0.22-0.28 eV, and that of thermal bleaching is about 0.75 eV. These centers are considered as produced by trapping the holes and liberating the interstitial silver ions. The initial sulphur centers are guessed as AgS-Ag^+ complexes formed under the condition of excess silver ions. The effects of hyperfine interaction by S^<33> isotopes are preliminarily described, in which the splitting constants are several gauss in both directions of the main axis of the g tensor.
- 社団法人応用物理学会の論文
- 1972-02-05
著者
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Sonoike Sanemi
Faculty Of Engineering Chuo University
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Morimoto Kazunari
Faculty Of Science And Engineering Chuo University
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MATSUI Mitate
Faculty of Science and Engineering, Chuo University
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Matsui Mitate
Faculty Of Science And Engineering Chuo University
関連論文
- The Distribution Coefficient of Sulphur Ions in Silver Chloride
- Saturation Properties of Paramagnetic Sulphur Centers in Silver Chloride Crystals
- Internal Friction Measurements of Silver Halide Crystals
- ENDOR Study of S Center in AgCl
- Anomalous Specific Heat of Silver Chloride Crystals Doped with Sulphur
- ESR Study of Silver Chloride Crystals Doped with Sulphur Ions and Mercury Ions
- The Profile of Sharp Peaks of Internal Friction in Silver Halide Crystals
- Effects of Impurity States on the Anomalous Specific Heat of AgCl:S
- Temperature Dependence of Surface Voltage of Silver Bromide
- ESR Study of Silver Specks in Silver Halide Crystals
- Light Scattering in Silver Halide Crystals
- ESR Study of Latent Image Specks in Silver Halide Crystals
- Luminescence of Doped Silver Chloride Crystals
- Study of Sharp Peaks in Internal Friction versus Temperature Curves in Silver Halide Crystals
- Observation of the Decomposition Processes of Thin Films of Silver Halide Crystals in Electron Microscope
- New Center Formation in Silver Halide Crystals Doped with Sulphur
- Charged Dislocations in Silver Halide Crystals