Biosynthesis of Acetylenic Compounds in Cultured Cells of Asparagus officinalis from [1-^<13>C]-and [U-^<13>C] Glucose

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概要

• 論文の詳細を見る

• The biosynthetic pathway of phenolics with an acetylenic group, 4-[5-(4-methoxyphenoxy)-3-penten-1-ynyl] phenol (1) and its related compounds, isolated from suspension-cultured cells of Asparagus officinalis L. (Liliaceae), was studied in feeding experiments using [1-^<13>C]-and [U-^<13>C] glucose. Analyses of the ^<13>C-NMR spectra of the methyl ether and acetate of the ^<13>C-labelled species of 1 indicated that the aromatic rings at both ends of the molecule are formed from shikimic acid. It was also assumed that the acetylenic carbons in the C_5 chain could be incorporated together with its adjacent aromatic ring through any phenethyl class compound derived from phenylpropanoids, and the propenylene carbon through glycolysis metabolites with C_3 carbon units.

• 公益社団法人日本薬学会の論文
• 1995-11-15

著者

• 本田 千恵

  Pharmaceutical Sciences Mukogawa Women's University

• Honda Chikako

  Departments Of Physical Chemistry Showa Pharmaceutical University

• 上硲 和輔

  Faculty of Pharmaceutical Sciences, Mukogawa Women's University

• 寺田 衣子

  Faculty of Pharmaceutical Sciences, Mukogawa Women's University

• 本田 千恵

  Faculty of Pharmaceutical Sciences, Mukogawa Women's University

• 竹山 志朱代

  Faculty of Pharmaceutical Sciences, Mukogawa Women's University

• 諏訪 紀代子

  Faculty of Pharmaceutical Sciences, Mukogawa Women's University

• Terada K

  Faculty Of Pharmaceutical Sciences Toho University

• Honda C

  School Of Pharmaceutical Sciences Mukogawa Women's University

• Suwa K

  School Of Pharmacy And Pharmaceutical Sciences Mukogawa Women's University

• 上硲 和輔

  Pharmaceutical Sciences Mukogawa Women's University

• 竹山 志朱代

  Pharmaceutical Sciences Mukogawa Women's University

• 諏訪 紀代子

  Faculty Of Pharmaceutical Sciences Mukogawa Women's Univesity

• Takeyama S

  School Of Pharmaceutical Sciences Mukogawa Women's University

• 上硲 和輔

  Faculty Of Pharmaceutical Sciences Mukogawa Women's University

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