Synthesis of Tricholomic Acid. III. Synthesis of DL-erythro-α-Amino-3-oxo-5-isoxazolidineacetic Acid (DL-Tricholomic Acid) and Its Optical Resolution

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概要

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• DL-erythro-α-Amino-3-oxo-5-isoxazolidineacetic acid (I) was synthesized from dialkyl β-hydroxyglutamate. Optical resolution afforded L- and D-isomers, of which the former was proved to be identical with tricholomic acid, a flycidal and tasty constituent of Tricholoma muscarium KAWAMURA. The D-isomer lacked the biological activities.

• 公益社団法人日本薬学会の論文
• 1969-05-25

著者

• 神谷 高明

  Chemical Research Laboratories, Research and Development Division, Takeda Chemical Industries, Ltd.

• 岩崎 英介

  Chemical Research Laboratories and Microbiological Research Laboratories, Central Research Division,

• 上柳 次三郎

  Microbiological Research Laboratories, Central Research Division, Takeda Chemical Industries, Ltd.

• 岩崎 英介

  Chemical Research Laboratories And Microbiological Research Laboratories Central Research Division T

• 神谷 高明

  Chemical Research Laboratories Research And Development Division Takeda Chemical Industries Ltd.

• 上柳 次三郎

  Microbiological Research Laboratories Central Research Division Takeda Chemical Industries Ltd.

• 上柳 次三郎

  Chemical Research Laboratories, Research and Development Division, Takeda Chemical Industries, Ltd.

• 丘 修

  Chemical Research Laboratories, Research and Development Division, Takeda Chemical Industries, Ltd.

• 丘 修

  Chemical Research Laboratories Research And Development Division Takeda Chemical Industries Ltd.

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• Synthesis of Tricholomic Acid, a Flycidal Amino Acid. I.
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• Synthesis of Tricholomic Acid.II

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