熱重量および示差走査熱量測定結果の速度論的解析法(第2報)

概要

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Kinetic analysis of thermal decomposition was carried out by using differential scanning calorimetry, derivative thermogravimetry, and thermogravimetry. 1) The thermal decomposition mechanism could be estimated by measuring the residual fraction (C_m) at a temperature when decomposition rate was maximum. The C_m was characteristic of reaction mechanism. 2) The activation energy could be estimated by measuring the difference between temperatures (T_d) of maximum decomposition rate at different heating rates, or measuring the T_d when the crystals decomposed to a certain fraction at different heating rates. The T_d was independent of reaction mechanism.
公益社団法人日本薬学会の論文
1984-03-25