Studies on the Catalytic Oxidation Reactions of Skatole using Cobalt Complexes
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概要
- 論文の詳細を見る
Oxygenation reactions of skatole catalyzed by N, N'-ethylenebis (salicylideniminato) Co (II) [Co (salen)], N, N'-ethylenebis (acetylacetoniminato) Co (II) [Co (acacen)], Co (II)-complex of α, β, γ, δ-tetra (p-methoxyphenyl) porphine [Co (p-OCH_3) TPP] and Co (II)-complex of phthalocyanine (CoPc) were investigated. Remarkable repression of the oxygenation was observed upon addition of a Lewis base such as pyridine, imidazole or N-methylimidazole to the reaction medium. This phenomenon was thought to indicate that the oxygenation proceeds through a ternary complex of the type skatole-Co-complex-O_2. The reaction rate constants and activation energies of all the reactions were also evaluated.
- 社団法人日本薬学会の論文
- 1981-06-25
著者
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上田 陽
Faculty of Pharmaceutical Sciences, Kyushu University
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藤井 卓
Faculty Of Pharmaceutical Sciences Kyushu University Identification Section Oita Prefectural Police
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小野 行雄
福山大学薬学部
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上田 陽
九州大学薬学部
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小野 行雄
Faculty of Pharmaceutical Sciences, Kyushu University
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香野 敬喜
Faculty of Pharmaceutical Sciences, Kyushu University
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上田 陽
Faculty Of Pharmaceutical Sciences Kyushu University
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