Reactions of Carbene Conjugated with 1-Azaazulene Moiety : Additions of 3-(2-Chloro-1-azaazulenyl)methylene with cis- and trans-Stibenes and p-Substituted Styrenes to Form 3-Cyclopropyl-1-azaazulenes
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概要
- 論文の詳細を見る
The addition reactions of 3-(2-chloro-1-azaazulenyl)methylene with cis- and trans-stilbenes proceeded in a stereospecific manner to afford the corresponding cyclopropane derivatives. The substitution effects on the relative rate ratio of the addition reactions of the carbene with styrenes having various substituents on the p-positions were measured to investigate the electronic nature of carbene.
- 公益社団法人日本薬学会の論文
- 1993-04-15
著者
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斉藤 勝裕
Department of Applied Chemistry, Nagoya Institute of Technology
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斉藤 勝裕
Department Of Applied Chemistry Nagoya Institute Of Technology
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高橋 憲助
Department Of Applied Chemistry Nagoya Institute Of Technology
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伏原 周志
Department of Applied Chemistry, Nagoya Institute of Technology
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阿部 憲孝
Department of Chemistry, Faculty of Science, Yamaguchi University
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伏原 周志
Department Of Applied Chemistry Nagoya Institute Of Technology
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阿部 憲孝
Department Of Chemistry Faculty Of Science Yamaguchi University
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- Aromatization and Hydrogen-Shift of 7-Substituted 1,3,5-Cycloheptatrienes in the Presence of Palladium(II) Acetate
- Reactions of Carbene Conjugated with 1-Azaazulene Moiety : Additions of 3-(2-Chloro-1-azaazulenyl)methylene with cis- and trans-Stibenes and p-Substituted Styrenes to Form 3-Cyclopropyl-1-azaazulenes
- Stereoselective [2π+4π]-Type Addition Reactions of Benzocyclobutadiene with 2-Substituted Tropones and 8,8-Dicyanoheptafulvene
- Introduciton of Acetoxyl Group in Tropone and Azulene Nuclei Using Palladium (II) Acetate : Reactions of 2-Aminotropones and Azulenes with Palladium (II) Acetate