Aromatization and Hydrogen-Shift of 7-Substituted 1,3,5-Cycloheptatrienes in the Presence of Palladium(II) Acetate

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概要

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• Reaction of 7-ethoxycarbonyl-1,3,5-cycloheptatrine with palladium(II) acetate afforded 2- and 4-formylbenzoic acid ethyl ester and diethyl maleate via aromatization, and a mixture of position isomers of the cycloheptatriene through hydrogen-shift. The reaction with 7-cyano-1,3,5-cycloheptatriene was also investigated. The reactions are considered to proceed through palladium complexes of the cycloheptatrienes and their norcaradiene isomers.

• 公益社団法人日本薬学会の論文
• 1993-12-15

著者

• 斉藤 勝裕

  Department of Applied Chemistry, Nagoya Institute of Technology

• 斉藤 勝裕

  Department Of Applied Chemistry Nagoya Institute Of Technology

• 小嵜 正敏

  Institute For Molecular Science The Graduate University For Advanced Studies

• 高橋 憲助

  Department Of Applied Chemistry Nagoya Institute Of Technology

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