Introduciton of Acetoxyl Group in Tropone and Azulene Nuclei Using Palladium (II) Acetate : Reactions of 2-Aminotropones and Azulenes with Palladium (II) Acetate
スポンサーリンク
概要
- 論文の詳細を見る
Reactiond of 2-(N, N-dimethylamino)- and 2-(N, N-diethylamino)tropones with palladium (II) acetate in benzene in the presence of sodium acetate afforded the corresponding 7-acetoxylated 2-aminotropones. A similar acetoxylation reaction proceeded with azulene to give 1-acetoxy- and 1,3-diacetoxyazulenes. On the other hand, phenylation at the 7-position occurred in the reaciton using 2-(N-methyl)anilinotoropone. The acetoxylations are considered to proceed through radical cation complexes formed through oxidation of amino groups by palladium.
- 公益社団法人日本薬学会の論文
- 1991-07-25
著者
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斉藤 勝裕
Department of Applied Chemistry, Nagoya Institute of Technology
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斉藤 勝裕
Department Of Applied Chemistry Nagoya Institute Of Technology
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小嵜 正敏
Institute For Molecular Science The Graduate University For Advanced Studies
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高橋 憲助
Department Of Applied Chemistry Nagoya Institute Of Technology
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阿部 憲孝
Department of Chemistry, Faculty of Science, Yamaguchi University
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小嵜 正敏
Department of Applied Chemistry, Nagoya Institute of Technology
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上西 和也
Department of Applied Chemistry, Nagoya Institute of Technology
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上西 和也
Department Of Applied Chemistry Nagoya Institute Of Technology
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阿部 憲孝
Department Of Chemistry Faculty Of Science Yamaguchi University
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- Aromatization and Hydrogen-Shift of 7-Substituted 1,3,5-Cycloheptatrienes in the Presence of Palladium(II) Acetate
- Reactions of Carbene Conjugated with 1-Azaazulene Moiety : Additions of 3-(2-Chloro-1-azaazulenyl)methylene with cis- and trans-Stibenes and p-Substituted Styrenes to Form 3-Cyclopropyl-1-azaazulenes
- Stereoselective [2π+4π]-Type Addition Reactions of Benzocyclobutadiene with 2-Substituted Tropones and 8,8-Dicyanoheptafulvene
- Introduciton of Acetoxyl Group in Tropone and Azulene Nuclei Using Palladium (II) Acetate : Reactions of 2-Aminotropones and Azulenes with Palladium (II) Acetate